Preparation of various xanthene derivatives over sulfonic acid functionalized imidazolium salts (SAFIS) as novel, highly efficient and reusable catalysts - 04/08/12
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Abstract |
In this work, some novel sulfonic acid functionalized imidazolium salts (SAFIS), as a new category of ionic liquids, are synthesized by eco-friendly and simple procedures, and used as highly efficient and reusable catalysts to promote the following one-pot multicomponent organic transformations under solvent-free conditions: (i) the synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes from β-naphthol (2eq.) and arylaldehydes (1eq.), (ii) the preparation of tetrahydrobenzo[a]xanthene-11-ones from β-naphthol, arylaldehydes and dimedone, and (iii) the synthesis of 1,8-dioxo-octahydroxanthenes from dimedone (2eq.) and aromatic aldehydes (1eq.). Environmentally benign, simple methodologies, easy workup procedure, clean reaction, short reaction time, high yield and easy preparation of the catalysts are some advantages of this work.
Le texte complet de cet article est disponible en PDF.Keywords : Sulfonic acid functionalized imidazolium salt, Ionic liquid, 14-aryl-14H-dibenzo[a,j]xanthene, Tetrahydrobenzo[a]xanthene-11-one, 1,8-dioxo-octahydroxanthene, Solvent-free
Plan
Vol 15 - N° 8
P. 719-736 - août 2012 Retour au numéroBienvenue sur EM-consulte, la référence des professionnels de santé.
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